Comprehensive 4Es (Energy, Exergy, Economic, Environmental) Analyses of Dedicated Mechanical Subcooled Vapour Compression Refrigeration Systems Using Low-GWP Refrigerants as R134a substitutes
DOI:
https://doi.org/10.22581/0379Keywords:
Coefficient of performance, Exergy Efficiency, Refrigerant Safety , TEWI Analysis, Annual Total Cost Rate , Low GWP Refrigerants AlternativesAbstract
With increasing restrictions on high GWP refrigerants in refrigeration system, the transition to efficient, climate-friendly alternatives has become necessary. Some efficient low GWP options fall within the A2/A2L flammability class, necessitating strict adherence to safety standards, introducing additional design and cost implications. Despite these challenges, integrated assessments that simultaneously address performance, environmental impact, safety requirements, and economic viability in a dedicated mechanical subcooling refrigeration system (DMS-VCRS) remain scarce.
This study presents a comprehensive parametric evaluation of seven R134A substitutes under the DMS-VCRS framework using 4Es (Energy, Exergy, Economic, Environmental) analysis. It includes TEWI-based environmental analysis and safety-economic assessments for A2/A2L refrigerants. The R134a substitute refrigerants that were examined in this work include R1234ze(E), R1234yf, R440A, R450A, R513A, R515A, and R152A. The model of the DMS-VCRS was carried out using STEAG Ebsilon Professional software with REFPROP 9.1 thermophysical property correlation. The model validation demonstrated excellent agreement with the literature (RMSE = 0.0334, MAPE < 3%, R² > 0.997).
Parametric studies investigated the influence of condenser temperatures, evaporator temperatures, degrees of subcooling, degrees of superheating, and refrigerant mass-flow ratios on thermodynamics, economics, and environmental impacts performance. R152A and R440A performed better than R134A, achieving a 7% increase in COP, a 6% increase in exergy efficiency, and a 13–22% reduction in Total Equivalent Warming Impact (TEWI) compared to R134A. Reliability-bounded operating ranges for subcooling degrees (22–39.5 °C) and superheating degrees (1.5–37.5 °C), along with other parameters, yielded optimal conditions at 34–37 °C condenser 1 temperature, −4 °C evaporator temperature, and 27.3–32.5 °C and 20–25 °C subcooling and superheating, respectively. The performance of 4Es was consistently and mildly impacted by variations in superheating and subcooling degrees. While indirect emissions from power consumption show a total TEWI (>85%). Their economic competitiveness is demonstrated by the fact that R152A and R440A had the lowest Annual Total Cost Rate (ATCR) (≈5% below R134a) and Total System Cost (TCR-SYS), which was roughly 9% higher than R134a but 12% lower than R1234yf. Although R152A and R440A are mildly flammable (A2), safe operation can be ensured under the IEC 60335-2-89 guideline through charge limitation, leak detection, and ventilation
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References
Calm, J. M. (2008). "The next generation of refrigerants – Historical review, considerations, and outlook." International Journal of Refrigeration, 31(7), 1123-1133.
Mota-Babiloni, A., Navarro-Esbrí, J., Molés, F., Barragán-Cervera, Á., Peris, B., & Verdú, G. (2016). A review of refrigerant R1234ze(E) recent investigations. Applied Thermal Engineering, 95, 211–222. https://doi.org/10.1016/j.applthermaleng.2015.09.055
Abas N, Kalair AR, Khan N, Haider A, Saleem Z, Saleem MS. Natural and synthetic refrigerants, global warming: a review. Renew Sustain Energy Rev 2018;90:557–69. https://doi.org/10.1016/j.rser.2018.03.099.
Mota-Babiloni, A., Makhnatch, P., & Khodabandeh, R. (2017). Recent investigations in HFCs substitution with lower GWP synthetic alternatives: Focus on energetic performance and environmental impact. International Journal of Refrigeration-Revue Internationale Du Froid. https://doi.org/10.1016/J.IJREFRIG.2017.06.026
Peixoto, R., Kuijpers, L., Polonara, F., & Maidment, G. (2017). Potential Impacts of the Montreal Protocol Kigali Amendment to the Choice of Refrigerant Alternatives. International Journal of Heat and Technology. https://doi.org/10.18280/IJHT.35SP0101
Llopis, R., Nebot-Andrés, L., Sánchez, D., Catalán-Gil, J., & Cabello, R. (2018). Subcooling methods for CO₂ refrigeration cycles: A review. International Journal of Refrigeration, 93, 269–310. https://doi.org/10.1016/j.ijrefrig.2018.06.010
K. S. Hmood, V. Apostol, H. Pop, V. Badescu, and E. Pop, “Drop-in and retrofit refrigerants as replacement possibilities of R134a in domestic/commercial refrigeration and automobile air conditioner applications”, Journal of Thermal Engineering, vol. 7, no. 7, pp. 1815–1835, 2021, doi:10.18186/thermal.1027435.
Aprea, C., Greco, A., & Maiorino, A. (2016). An experimental investigation on the substitution of HFC134a with HFO1234YF in a domestic refrigerator. Applied Thermal Engineering, 106, 959-967. https://doi.org/10.1016/j.applthermaleng.2016.06.098
Minor, B., Montoya, C., & Kasa, F. S. (2010). HFO-1234yf performance in a beverage cooler. International Refrigeration and Air Conditioning Conference at Purdue, Paper 1036.
Navarro-Esbrí, J., Mendoza-Miranda, J. M., Mota-Babiloni, A., Barragán-Cervera, Á., & Belman-Flores, J. M. (2013). Experimental analysis of R1234yf as a drop-in replacement for R134a in a vapor compression system. International Journal of Refrigeration, 36(3), 870–880. https://doi.org/10.1016/j.ijrefrig.2012.12.014
Mota-Babiloni, A., Navarro-Esbrí, J., Barragán-Cervera, Á., Molés, F., & Peris, B. (2015). Analysis based on EU Regulation No 517/2014 of new HFC/HFO mixtures as alternatives of high GWP refrigerants in refrigeration and HVAC systems. International Journal of Refrigeration, 52, 21–31. https://doi.org/10.1016/j.ijrefrig.2014.12.021
Nawaz, K., Shen, B., Elatar, A., Baxter, V. D., & Abdelaziz, O. (2017). R1234yf and R1234ze(E) as low-GWP refrigerants for residential heat pump water heaters. International Journal of Refrigeration-Revue Internationale Du Froid. https://doi.org/10.1016/J.IJREFRIG.2017.06.031
Liu, B., Yang, Z., Zhang, C., Lv, Z., Chen, Y., & Chen, S. (2022). Evaluation of a low-GWP and nonflammable blend as a new alternative for R134a in the heat pump system. International Journal of Refrigeration-Revue Internationale Du Froid. https://doi.org/10.1016/j.ijrefrig.2022.06.029
Bukola O. Bolaji (2020), Theoretical assessment of new low global warming potential refrigerant mixtures as eco-friendly alternatives in domestic refrigeration systems, https://doi.org/10.1016/j.sciaf.2020.e00632
Li, G. (2017). Comprehensive investigation of transport refrigeration life cycle climate performance. Sustainable Energy Technologies and Assessments, 21, 33-49.
Agarwal, S., Arora, A., & Arora, B. B. (2020). Exergy Analysis of Dedicated Mechanically Subcooled Vapour Compression Refrigeration Cycle Using HFC-R134a, HFO-R1234ze and R1234yf. In: Advances in Energy and Built Environment, Springer, Singapore, pp. 23–33. https://doi.org/10.1007/978-981-13-7557-6_3
Ansari, N.A., Arora, A., Samsher, Manjunath, K. (2020). The Effect of Eco-friendly Refrigerants on Performance of Vapor Compression Refrigeration System with Dedicated Mechanical Subcooling. In: Zhang, G., Kaushika, N., Kaushik, S., Tomar, R. (eds) Advances in Energy and Built Environment. Lecture Notes in Civil Engineering , vol 36. Springer, Singapore. https://doi.org/10.1007/978-981-13-7557-6_4
Solanki, N., Arora, A. & Singh, R.K. Performance enhancement and environmental analysis of vapor compression refrigeration system with dedicated mechanical subcooling. Int. J. Air-Cond. Ref. 31, 26 (2023). https://doi.org/10.1007/s44189-023-00042-8
T. S. Mogaji, A. Awolala, O. Z. Ayodeji, P. B. Mogaji and D. E. Philip (2020), COP enhancement of vapour compression refrigeration system using dedicated mechanical subcooling cycle. T. S. Nigerian Journal of Technology (NIJOTECH) Vol. 39, No. 3, July 2020, pp. 776 – 784, http://dx.doi.org/10.4314/njt.v39i3.17
Wu, J., & Wang, C. C. (2010). Performance analysis of a vapor compression refrigeration system with liquid-line subcooling. Applied Thermal Engineering, 30(10), 1245–1252.
Ahamed J.U., R. Saidur, H.H. Masjuki, "A review on exergy analysis of vapor compression refrigeration system," Renewable and Sustainable Energy Reviews, vol. 15, no. 3, pp. 1593-1600, 2011.
Arora, A., Singh, N. K., Monga, S., & Kumar, O. (2011). Energy and exergy analysis of a combined transcritical CO2 compression refrigeration and single effect H2O-LiBr vapor absorption system. International Journal of Exergy, 13(3), 395-415.
Y. Alhendal, A. Gomaa, G. Bedair, and A. Kalendar, "Thermal Performance Analysis of Low-GWP Refrigerants in Automotive Air-Conditioning System," Advances in material science and Engineering, vol. 2020, Article ID 7967812, 2020.
Wang, Y., Wang, H., & Ma, Z. (2019). Techno-economic analysis of low-GWP refrigerants in refrigeration systems. Energy Reports, 5, 207–215.
Belman-Flores, J. M., Rangel-Hernández, V. H., Usón, S., & Rubio-Maya, C. (2017). Energy and exergy analysis of R1234yf as drop-in replacement for R134a in a domestic refrigeration system. Energy, 132, 116–125. https://doi.org/10.1016/j.energy.2017.05.074
Yang, Z., Wang, X., & Li, Y. (2021). Thermodynamic and economic analysis of a dedicated mechanical subcooling system for refrigeration applications. Energy, 225, 120271. https://doi.org/10.1016/j.energy.2021.120271
Makhnatch, P., Mota-Babiloni, A., López-Belchí, A., & Khodabandeh, R. (2019). R450A and R513A as lower GWP mixtures for high ambient temperature countries: Experimental comparison with R134a. Energy, 166, 223–235. https://doi.org/10.1016/j.energy.2018.09.001
ASHRAE. (2022). ANSI/ASHRAE Standard 34-2022: Designation and Safety Classification of Refrigerants. Atlanta: American Society of Heating, Refrigerating and Air-Conditioning Engineers.
Direk, M., Mert, M. S., Soylu, E., & Yuksel, F. (2019). Experimental investigation of an automotive air conditioning system using R444A and R152a refrigerants as alternatives to R134a. International Journal of Refrigeration, 106, 396–406. https://doi.org/10.1016/j.ijrefrig.2019.06.008
Saengsikhiao, P., Taweekun, J., Maliwan, K., & Theppaya, T. (2020). Investigation and analysis of R463A as an alternative refrigerant to R404A with lower global warming potential. International Journal of Refrigeration, 118, 58–68. https://doi.org/10.1016/j.ijrefrig.2020.04.016
Gas Servei. (2024). Technical Data Sheet – R-513A. Retrieved from https://gas-servei.com
Chen, Q., Yan, G., & Yu, J. (2017). Performance analysis of an ejector enhanced refrigeration cycle with R290/R600a for application in domestic refrigerator/freezers. Applied Thermal Engineering, 120, 581–592. https://doi.org/10.1016/j.applthermaleng.2017.04.027
Kotas, T. J. (2012). The exergy method of thermal plant analysis. Paragon Publishing.
Dincer, I., and Kanoglu, M., Refrigeration Systems and Applications, 2nd ed. Hoboken, NJ: John Wiley & Sons, 2010.
Roy, R., Mandal, B.K. Thermo-economic analysis and multi-objective optimization of vapour cascade refrigeration system using different refrigerant combinations. J Therm Anal Calorim 139, 3247–3261 (2020). https://doi.org/10.1007/s10973-019-08710-x
Aminyavari M, Najafi B, Shirazi A, Rinaldi F. Exergetic, economic and environmental (3E) analyses, and multi-objective optimization of a CO2/NH3 cascade refrigeration system. Appl Therm Eng. 2014;65(1–2):42–50.
Mosaffa AH, Farshi LG, Ferreira CI, Rosen MA. Exergoeconomic and environmental analyses of CO2/NH3 cascade refrigeration systems equipped with different types of flash tank intercoolers. Energy Convers Manage. 2016;117:442–53.
Wang J, Zhai ZJ, Jing Y, Zhang C. Particle swarm optimization for redundant building cooling heating and power system. Appl Energy. 2010;87(12):3668–79.
Hamza, A., Khan, T.A. Comparative Performance of Low-GWP Refrigerants as Substitutes for R134a in a Vapor Compression Refrigeration System. Arab J Sci Eng 45, 5697–5712 (2020). https://doi.org/10.1007/s13369-020-04525-3
Dincer, I. and Rosen, M. A., Exergy: Energy, Environment and Sustainable Development, Amsterdam: Elsevier, 2007.
Bejan A., Advanced Engineering Thermodynamics, 4th ed. Hoboken, NJ: John Wiley & Sons, 2016.
Bolaji, B. O., & Huan, Z. (2013). Ozone depletion and global warming: Case for the use of natural refrigerant–a review. Renewable and Sustainable Energy Reviews, 18, 49-54.
Corberán, J. M., Martínez, I. O., & Gonzálvez, J. (2008). Charge optimization study of a reversible water-to-water propane heat pump. International Journal of Refrigeration, 31(4), 716-726.
Qureshi, B. A., & Zubair, S. M. (2012). The impact of fouling on performance of a vapor compression refrigeration system with integrated mechanical sub-cooling system. Applied Energy, 92, 750-762.
Farsi, A., Mohammadi, S. M. H., & Ameri, M. (2017). Thermo-economic comparison of three configurations of combined supercritical CO2 refrigeration and multi-effect desalination systems. Applied Thermal Engineering, 112, 855-870.
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